conversion in amines | iTeachChem | Page 1

timber dome Sep 17, 2024, 7:59 AM

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just wanna know what happens and the logic between them . and if theres any short trick to do this conversion. thanks

stray spindleBOT Sep 17, 2024, 8:13 AM

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Note for OP

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tepid zephyr Sep 17, 2024, 8:15 AM

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https://www.masterorganicchemistry.com/2018/12/03/reactions-of-diazonium-salts-sandmeyer-and-related-reactions/#four

Master Organic Chemistry

James Ashenhurst

Reactions of Diazonium Salts: Sandmeyer and Related Reactions

Aromatic amines react with nitrous acid to give diazonium salts. These can undergo further reactions (such as the Sandmeyer reaction) giving useful products

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Check diazo coupling

glass wing Sep 17, 2024, 9:13 AM

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Basically addition of electrophile (here diazonium salt) on the benzene ring, for phenol and aniline, para position coupling is exclusively major pdt, like in this pic, it takes place in mild basic medium, but only for aniline it's mild acidic, they are mild not strong note that, or else for example aniline would take up a hydrogen with it's lone pair in strong acidic medium, which ruins the coupling, these are some basic stuff

tepid zephyr Sep 28, 2024, 3:37 AM

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timber dome just wanna know what happens and the logic between them . and if theres any shor...

sorted?

timber dome Oct 3, 2024, 3:10 AM

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tepid zephyr sorted?

yes thanks

tepid zephyr Oct 3, 2024, 3:10 AM

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timber dome yes thanks

Nice